Bubbles—a glass-ceramic plague

Glass-ceramics (GC) were discovered by S. D. Stookey approximately 65 years ago.1 GC research and technology can now be considered a mature field described by over 10,000 scientific articles and 5,000 patents, although many other GC may still be discovered, and a plethora of issues pertaining to their development and production remain to be solved.1–4

Deubener et al.5 (2018) recently described GCs thus: “Glass-ceramics are inorganic, non-metallic materials prepared by controlled crystallization of glasses via different processing methods. They contain at least one type of functional crystalline phase and a residual glass. The volume fraction crystallized may vary from ppm to almost 100%.” GCs can be produced by sintering with concurrent surface crystallization of crushed glass powders or more traditionally by catalyzed internal crystallization of monolithic glass articles.1–5

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