Energetics and structures of halide perovskites: A thermochemistry perspective

Perovskites are universal materials that find applications in many realms, including energy storage and conversion, photovoltaics, photocatalysts, thermoelectrics, supercapacitors, and superconductors.

The concept of perovskite, named after Russian mineralogist Lev Perovski, originally referred to the mineral CaTiO3. Now, the term describes a rich landscape of materials bearing stoichiometric and structural resemblance to CaTiO3, generically known as ABX3, where A and B are metal cations of different ionic sizes, and X represents an anion bonding to both.

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